Origin of Magnetization in Silica-coated Fe3O4 Nanoparticles Revealed by Soft X-ray Magnetic Circular Dichroism
نویسندگان
چکیده
Magnetite (Fe3O4) nanoparticles (NPs) and SiO2-coated Fe3O4 have successfully been synthesized using co-precipitation modified Stöber methods, respectively. The samples were characterized X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, high-resolution transmission electron microscopy (HRTEM), vibrating sample magnetometer (VSM) techniques, absorption spectroscopy (XAS), magnetic circular dichroism (XMCD). XRD FTIR data confirmed the structural configuration of a single-phase successful formation NPs. also that we succeeded to synthesize nano-meter size HRTEM images showed increasing thickness with addition Tetraethyl Orthosilicate (TEOS). Room temperature VSM analysis behaviour its variations occurred after SiO2 coating. is further authenticated by XAS spectra which cleared about existence shells transformed crystal as well local structures magnetite We performed XMCD measurements, powerful element-specific technique find out origin magnetization in NPs, verified decrease
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ژورنال
عنوان ژورنال: Brazilian Journal of Physics
سال: 2022
ISSN: ['0103-9733', '1678-4448']
DOI: https://doi.org/10.1007/s13538-022-01102-x